NWChem/examples/pspw/C2.out
2000-11-04 02:54:11 +00:00

734 lines
26 KiB
Text

Creating: host=fermi, user=d3g681,
file=/msrc/home/d3g681/nwchem/bin/SOLARIS_ULTRA/nwchem, port=40777
argument 1 = C2
argument 2 = -master
argument 3 = fermi.emsl.pnl.gov
argument 4 = 40777
argument 5 = 1
argument 6 = 2
argument 7 = 0
argument 8 = 0
Unable to open C2 --- appending .nw
Northwest Computational Chemistry Package (NWChem) 4.0
------------------------------------------------------
Environmental Molecular Sciences Laboratory
Pacific Northwest National Laboratory
Richland, WA 99352
COPYRIGHT (C) 1994, 1995, 1996, 1997, 1998, 1999, 2000
Pacific Northwest National Laboratory,
Battelle Memorial Institute.
>>> All Rights Reserved <<<
DISCLAIMER
----------
This material was prepared as an account of work sponsored
by an agency of the United States Government. Neither the
United States Government nor the United States Department
of Energy, nor Battelle, nor any of their employees, MAKES
ANY WARRANTY, EXPRESS OR IMPLIED, OR ASSUMES ANY LEGAL
LIABILITY OR RESPONSIBILITY FOR THE ACCURACY, COMPLETENESS,
OR USEFULNESS OF ANY INFORMATION, APPARATUS, PRODUCT,
SOFTWARE, OR PROCESS DISCLOSED, OR REPRESENTS THAT ITS USE
WOULD NOT INFRINGE PRIVATELY OWNED RIGHTS.
LIMITED USE
-----------
This software (including any documentation) is being made
available to you for your internal use only, solely for use
in performance of work directly for the U.S. Federal
Government or work under contracts with the U.S. Department
of Energy or other U.S. Federal Government agencies. This
software is a version which has not yet been evaluated and
cleared for commercialization. Adherence to this notice
may be necessary for the author, Battelle Memorial
Institute, to successfully assert copyright in and
commercialize this software. This software is not intended
for duplication or distribution to third parties without
the permission of the Manager of Software Products at
Pacific Northwest National Laboratory, Richland,
Washington, 99352.
ACKNOWLEDGMENT
--------------
This software and its documentation were produced with
Government support under Contract Number DE-AC06-76RLO-1830
awarded by the United States Department of Energy. The
Government retains a paid-up non-exclusive, irrevocable
worldwide license to reproduce, prepare derivative works,
perform publicly and display publicly by or for the
Government, including the right to distribute to other
Government contractors.
Job information
---------------
hostname = fermi
program = /msrc/home/d3g681/nwchem/bin/SOLARIS_ULTRA/nwchem
date = Sat Oct 14 12:33:33 2000
compiled = Sat Oct 14 09:35:23 PDT 2000
source = /msrc/home/d3g681/nwchem
nwchem branch = Development
input = C2.nw
prefix = C2.
data base = /tmp/C2.db
status = startup
nproc = 2
time left = -1s
Memory information
------------------
heap = 6553589 doubles = 52.4 Mbytes
stack = 6553598 doubles = 52.4 Mbytes
global = 13107200 doubles = 104.9 Mbytes (distinct from heap & stack)
total = 26214387 doubles = 209.7 Mbytes
verify = yes
hardfail = no
Directory information
---------------------
0 permanent = /tmp
0 scratch = /tmp
NWChem Input Module
-------------------
C2
--
------
auto-z
------
Geometry "geometry" -> ""
-------------------------
Output coordinates in a.u. (scale by 1.000000000 to convert to a.u.)
No. Tag Charge X Y Z
---- ---------------- ---------- -------------- -------------- --------------
1 C 6.0000 1.20000000 0.00000000 0.00000000
2 C 6.0000 -1.20000000 0.00000000 0.00000000
Atomic Mass
-----------
C 12.000000
Effective nuclear repulsion energy (a.u.) 15.0000000000
Nuclear Dipole moment (a.u.)
----------------------------
X Y Z
---------------- ---------------- ----------------
0.0000000000 0.0000000000 0.0000000000
Z-matrix (autoz)
--------
Units are Angstrom for bonds and degrees for angles
Type Name I J K L M Value
----------- -------- ----- ----- ----- ----- ----- ----------
1 Stretch 1 2 1.27003
==============================================================================
internuclear distances
------------------------------------------------------------------------------
center one | center two | atomic units | a.u.
------------------------------------------------------------------------------
2 C | 1 C | 2.40000 | 2.40000
------------------------------------------------------------------------------
number of included internuclear distances: 1
==============================================================================
>>>> PSPW Serial Module - 1d pseudopotential solver <<<<
All electron atom solver
Atom name: C
Zcharge : 6.000000e+00
Amass : 1.200000e+01
Ncore : 1
Nvalence : 2
: restricted calculation
------ Solver information ------
solver type : Pauli
hartree type : On
exchange type : Dirac
alpha : 0.666667
correlation type : Vosko parameterization
Solver iterations: 22
------- Grid information -------
Zcharge : 6.000000e+00
amesh : 1.005000e+00
R_max : 4.467913e+01
Ngrid : 2785
------------------------------------------------------------
n l population Eigenvalue Outer Peak
1 s 2.00 -9.952135e+00 1.743589e-01
2 s 2.00 -5.012954e-01 1.213506e+00
2 p 2.00 -1.990710e-01 1.189537e+00
------------------------------------------------------------
charge = 6.000000e+00
core charge = 2.000000e+00
Total E = -3.744197e+01
E_Hartree = 1.763555e+01
<Vh> = 3.527111e+01
E_exchange = -4.358252e+00
<Vx> = -5.811003e+00
E_correlation = -3.729106e-01
<Vc> = -4.187471e-01
Hamann pseudopotential check
l rcore rmatch E in E psp norm test slope test
0 0.800000 1.978409 -0.501295 -0.501295 1.000000 1.000007
1 0.850000 2.175060 -0.199071 -0.199071 1.000000 1.000008
2 0.850000 2.121490 -0.199071 -0.199071 1.000000 1.000000
PSP solver information
Atom name: C
Zcharge : 4.000000e+00
Nvalence : 3
: restricted calculation
------ Solver information ------
solver type : Hamann
hartree type : On
exchange type : Dirac
alpha : 0.666667
correlation type : Vosko parameterization
----------------------------------------------------------------------------
n l population Ecut Rcut Outer Peak
1 s 2.00 -5.012954e-01 8.000000e-01 1.225672e+00
2 p 2.00 -1.990710e-01 8.500000e-01 1.050089e+00
3 d 0.00 -1.990710e-01 8.500000e-01 4.467913e+01
----------------------------------------------------------------------------
Pseudopotential Charge: 4.000000
Total E = -5.339938e+00
E_Hartree = 4.359439e+00
<Vh> = 8.718878e+00
E_exchange = -1.176866e+00
<Vx> = -1.569155e+00
E_correlation = -1.935145e-01
<Vc> = -2.214593e-01
Outputing pseudowavefunctions: C.psw.plt
Outputing pseudopotentials: C.psp.plt
Creating datafile for Kleinman-Bylander input: C.psp
+ Appending pseudopotentials: s thru d
+ Appending pseudowavefunctions: s thru d
Outputing all-electron wavefunctions: C.1s C.2s C.2p C.3d
Outputing atom density: C.dns.plt
Outputing core density: C.cdns.plt
Outputing core density gradient: C.cddns.plt
Outputing semicore density: C.sdns.plt
Outputing semicore density gradient: C.sddns.plt
Outputing all-electron potential(non-screened): C.pot.plt
>>> JOB COMPLETED AT Sat Oct 14 12:33:36 2000 <<<
>>>> PSPW Serial Module - psp_generator <<<<
Task times cpu: 0.0s wall: 0.0s
NWChem Input Module
-------------------
>>>> PSPW Serial Module - psp_formatter <<<<
********************************************
* *
* KBPPV3 - Pseudopotential Formatter *
* *
* version last updated 4/15/99 *
* *
* This code was written by Eric J. Bylaska *
* and was based upon algorithms and code *
* developed by the group of *
* Prof. John H. Weare *
********************************************
>>> JOB STARTED AT Sat Oct 14 12:33:38 2000 <<<
Pseudpotential Data
-------------------
atom :C
charge : 4.0000000000000
mass no. : 12.000000000000
highest angular component : 2
highest angular component used : 2
local potential used : 0
cutoffs: 0.800 0.850 0.850
Simulation Cell
---------------
boundry: periodic
ngrid : 32 32 32
unita : 20.000 0.000 0.000
0.000 20.000 0.000
0.000 0.000 20.000
>>> JOB COMPLETED AT Sat Oct 14 12:33:38 2000 <<<
>>> JOB COMPLETED AT Sat Oct 14 12:33:38 2000 <<<
Task times cpu: 2.7s wall: 2.7s
NWChem Input Module
-------------------
>>>> PSPW Serial Module - wavefunction_initializer <<<<
writing <spin= 1,psi= 1> - ( 0 0 0 : 0)
writing <spin= 1,psi= 2> - ( 1 0 0 : -1)
writing <spin= 1,psi= 3> - ( 0 1 0 : -1)
writing <spin= 1,psi= 4> - ( 0 0 1 : -1)
JOB HAS BEEN COMPLETED. CODE= 0
>>> JOB COMPLETED AT Sat Oct 14 12:33:38 2000 <<<
Task times cpu: 0.0s wall: 0.0s
NWChem Input Module
-------------------
>>>> PSPW Parallel Module - steepest_descent <<<<
****************************************************
* *
* Car-Parrinello microcluster calculation *
* *
* [ steepest descent minimization ] *
* *
* [ NortWest Chemistry implementation ] *
* *
* version #5.00 06/01/99 *
* *
* This code was developed by Eric J. Bylaska, *
* and was based upon algorithms and code *
* developed by the group of Prof. John H. Weare *
* *
****************************************************
>>> JOB STARTED AT Sat Oct 14 12:33:38 2000 <<<
================ input data ========================
number of processors used: 2
options:
ionic motion = no
boundry conditions = periodic (version3)
electron spin = restricted
exchange-correlation = Vosko et al parameterization
elements involved in the cluster:
1: C mass no.: 12.0 core charge: 4. lmax=2
highest angular component : 2
local potential used : 0
number of non-local projections: 8
cutoff = 0.800 0.850 0.850
atomic composition:
C : 2
initial position of ions:
1 C ( 1.20000 0.00000 0.00000 )
2 C ( -1.20000 0.00000 0.00000 )
G.C. ( 0.00000 0.00000 0.00000 )
C.O.M. ( 0.00000 0.00000 0.00000 )
number of electrons: spin up= 4 spin down= 4 ( fourier space)
supercell:
lattice: a1=< 20.000 0.000 0.000 >
a2=< 0.000 20.000 0.000 >
a3=< 0.000 0.000 20.000 >
b1=< 0.314 0.000 0.000 >
b2=< 0.000 0.314 0.000 >
b3=< 0.000 0.000 0.314 >
volume : 8000.0
density cutoff= 12.633 fft= 32x 32x 32( 8536 waves 4268 per task)
wavefnc cutoff= 12.633 fft= 32x 32x 32( 8536 waves 4268 per task)
ewald summation: cut radius= 6.37 and 1
mandelung= 1.76011750
technical parameters:
time step= 51.80 fictacious mass= 400000.0
tolerance=.100E-08 (energy) 0.100E-08 (electron) 0.100E-03 (ion)
================ iteration =========================
>>> ITERATION STARTED AT Sat Oct 14 12:33:39 2000 <<<
100 -0.1096490716E+02 -0.21168E-02 0.21211E-04 0.00000E+00
200 -0.1096836100E+02 -0.66677E-06 0.85655E-07 0.00000E+00
300 -0.1096837385E+02 -0.24808E-08 0.34220E-09 0.00000E+00
400 -0.1096837390E+02 -0.97845E-11 0.13747E-11 0.00000E+00
*** tolerance ok. iteration terminated.
>>> ITERATION ENDED AT Sat Oct 14 12:34:46 2000 <<<
============= summary of results =================
final position of ions:
1 C ( 1.20000 0.00000 0.00000 )
2 C ( -1.20000 0.00000 0.00000 )
G.C. ( 0.00000 0.00000 0.00000 )
C.O.M. ( 0.00000 0.00000 0.00000 )
number of electrons: spin up= 4.00000 down= 4.00000 (real space)
total energy : -0.1096837390E+02 ( -0.54842E+01/ion)
total orbital energy: -0.3320239525E+01 ( -0.83006E+00/electron)
hartree energy : 0.1073989023E+02 ( 0.26850E+01/electron)
exc-corr energy : -0.3057255333E+01 ( -0.76431E+00/electron)
ion-ion energy : 0.2151636854E+01 ( 0.10758E+01/ion)
K.S. kinetic energy : 0.6764972291E+01 ( 0.16912E+01/electron)
K.S. V_l energy : -0.2516750262E+02 ( -0.62919E+01/electron)
K.S. V_nl energy : -0.2400115325E+01 ( -0.60003E+00/electron)
K.S. V_Hart energy : 0.2147978046E+02 ( 0.53699E+01/electron)
K.S. V_xc energy : -0.3997374330E+01 ( -0.99934E+00/electron)
Virial Coefficient : -0.1490798688E+01
orbital energies:
-0.2888802E+00 ( -7.861eV)
-0.2888802E+00 ( -7.861eV)
-0.3754851E+00 ( -10.218eV)
-0.7068742E+00 ( -19.235eV)
=== Spin Contamination ===
<Sexact^2> = 0.
<S^2> = 0.
== Center of Charge ==
spin up ( 0.0000, 0.0000, 0.0000 )
spin down ( 0.0000, 0.0000, 0.0000 )
total ( 0.0000, 0.0000, 0.0000 )
ionic ( 0.0000, 0.0000, 0.0000 )
== Molecular Dipole ==
mu = ( 0.0002, 0.0001, 0.0001 ) au
|mu| = 0.0002 au, 0.0006 Debye
-----------------
cputime in seconds
prologue : 1.0643560000000
main loop : 66.089232000000
epilogue : 0.11219399999999
total : 67.265782000000
cputime/step: 0.16522308000000
-------------------------------
Time spent doing:
FFTs : 27.841062000000
dot products : 2.4546719999997
orthonormalization : 4.6994980000000
exchange correlation : 13.563120000000
local pseudopotentials : 1.8092080000000
non-local pseudopotentials : 11.674768000000
hartree potentials : 0.16958799999985
structure factors : 0.37745000000020
masking : 0.
>>> JOB COMPLETED AT Sat Oct 14 12:34:46 2000 <<<
Task times cpu: 63.0s wall: 67.3s
NWChem Input Module
-------------------
>>>> PSPW Parallel Module - steepest_descent <<<<
****************************************************
* *
* Car-Parrinello microcluster calculation *
* *
* [ steepest descent minimization ] *
* *
* [ NortWest Chemistry implementation ] *
* *
* version #5.00 06/01/99 *
* *
* This code was developed by Eric J. Bylaska, *
* and was based upon algorithms and code *
* developed by the group of Prof. John H. Weare *
* *
****************************************************
>>> JOB STARTED AT Sat Oct 14 12:34:46 2000 <<<
================ input data ========================
number of processors used: 2
options:
ionic motion = yes
boundry conditions = periodic (version3)
electron spin = restricted
exchange-correlation = Vosko et al parameterization
elements involved in the cluster:
1: C mass no.: 12.0 core charge: 4. lmax=2
highest angular component : 2
local potential used : 0
number of non-local projections: 8
cutoff = 0.800 0.850 0.850
atomic composition:
C : 2
initial position of ions:
1 C ( 1.20000 0.00000 0.00000 )
2 C ( -1.20000 0.00000 0.00000 )
G.C. ( 0.00000 0.00000 0.00000 )
C.O.M. ( 0.00000 0.00000 0.00000 )
number of electrons: spin up= 4 spin down= 4 ( fourier space)
supercell:
lattice: a1=< 20.000 0.000 0.000 >
a2=< 0.000 20.000 0.000 >
a3=< 0.000 0.000 20.000 >
b1=< 0.314 0.000 0.000 >
b2=< 0.000 0.314 0.000 >
b3=< 0.000 0.000 0.314 >
volume : 8000.0
density cutoff= 12.633 fft= 32x 32x 32( 8536 waves 4268 per task)
wavefnc cutoff= 12.633 fft= 32x 32x 32( 8536 waves 4268 per task)
ewald summation: cut radius= 6.37 and 1
mandelung= 1.76011750
technical parameters:
time step= 5.80 fictacious mass= 400000.0
tolerance=.100E-08 (energy) 0.100E-08 (electron) 0.100E-03 (ion)
================ iteration =========================
>>> ITERATION STARTED AT Sat Oct 14 12:34:47 2000 <<<
100 -0.1096845099E+02 -0.18911E-01 0.27520E-07 0.46835E-03
200 -0.1096847880E+02 -0.47945E-07 0.14455E-07 0.32209E-03
300 -0.1096849384E+02 -0.25935E-07 0.77456E-08 0.23204E-03
400 -0.1096850215E+02 -0.14328E-07 0.45933E-08 0.16978E-03
500 -0.1096850677E+02 -0.79772E-08 0.26888E-08 0.12517E-03
600 -0.1096850936E+02 -0.44573E-08 0.15568E-08 0.92684E-04
700 -0.1096851081E+02 -0.24953E-08 0.89375E-09 0.68827E-04
800 -0.1096851162E+02 -0.13985E-08 0.50983E-09 0.51211E-04
900 -0.1096851207E+02 -0.78444E-09 0.28941E-09 0.38158E-04
*** tolerance ok. iteration terminated.
>>> ITERATION ENDED AT Sat Oct 14 12:37:39 2000 <<<
============= summary of results =================
final position of ions:
1 C ( 1.19120 0.00000 0.00000 )
2 C ( -1.19120 0.00000 0.00000 )
G.C. ( 0.00000 0.00000 0.00000 )
C.O.M. ( 0.00000 0.00000 0.00000 )
number of electrons: spin up= 4.00000 down= 4.00000 (real space)
total energy : -0.1096851207E+02 ( -0.54843E+01/ion)
total orbital energy: -0.3326917317E+01 ( -0.83173E+00/electron)
hartree energy : 0.1078436213E+02 ( 0.26961E+01/electron)
exc-corr energy : -0.3063953878E+01 ( -0.76599E+00/electron)
ion-ion energy : 0.2200520751E+01 ( 0.11003E+01/ion)
K.S. kinetic energy : 0.6790253317E+01 ( 0.16976E+01/electron)
K.S. V_l energy : -0.2526461005E+02 ( -0.63162E+01/electron)
K.S. V_nl energy : -0.2415084333E+01 ( -0.60377E+00/electron)
K.S. V_Hart energy : 0.2156872425E+02 ( 0.53922E+01/electron)
K.S. V_xc energy : -0.4006200496E+01 ( -0.10016E+01/electron)
Virial Coefficient : -0.1489954816E+01
orbital energies:
-0.2902312E+00 ( -7.898eV)
-0.2902312E+00 ( -7.898eV)
-0.3739781E+00 ( -10.177eV)
-0.7090181E+00 ( -19.294eV)
=== Spin Contamination ===
<Sexact^2> = 0.
<S^2> = 0.
== Center of Charge ==
spin up ( 0.0000, 0.0000, 0.0000 )
spin down ( 0.0000, 0.0000, 0.0000 )
total ( 0.0000, 0.0000, 0.0000 )
ionic ( 0.0000, 0.0000, 0.0000 )
== Molecular Dipole ==
mu = ( 0.0002, 0.0001, 0.0001 ) au
|mu| = 0.0002 au, 0.0006 Debye
-----------------
cputime in seconds
prologue : 0.95622200000001
main loop : 172.83436200000
epilogue : 0.12302199999999
total : 173.91360600000
cputime/step: 0.19203818000000
-------------------------------
Time spent doing:
FFTs : 63.184116000001
dot products : 8.4258879999982
orthonormalization : 9.2991919999998
exchange correlation : 30.640298000000
local pseudopotentials : 5.1572879999995
non-local pseudopotentials : 44.455540000001
hartree potentials : 0.38127400000025
structure factors : 1.5787939999993
masking : 0.
>>> JOB COMPLETED AT Sat Oct 14 12:37:40 2000 <<<
Task times cpu: 162.7s wall: 173.9s
NWChem Input Module
-------------------
Summary of allocated global arrays
-----------------------------------
No active global arrays
GA Statistics for process 0
------------------------------
create destroy get put acc scatter gather read&inc
calls: 0 0 0 0 0 0 0 0
bytes total: 0.00e+00 0.00e+00 0.00e+00 0.00e+00 0.00e+00 0.00e+00
bytes remote: 0.00e+00 0.00e+00 0.00e+00 0.00e+00 0.00e+00 0.00e+00
Max memory consumed for GA by this process: 0 bytes
MA_summarize_allocated_blocks: starting scan ...
MA_summarize_allocated_blocks: scan completed: 0 heap blocks, 0 stack blocks
MA usage statistics:
allocation statistics:
heap stack
---- -----
current number of blocks 0 0
maximum number of blocks 61 23
current total bytes 0 0
maximum total bytes 2948652 2436604
maximum total K-bytes 2949 2437
maximum total M-bytes 3 3
ACKNOWLEDGEMENT
---------------
Please use the following acknowledgement where appropriate
for results obtained with NWChem:
High Performance Computational Chemistry Group, "NWChem, A
Computational Chemistry Package for Parallel Computers,
Version 4.0" (2000), Pacific Northwest National Laboratory,
Richland, Washington 99352-0999, USA.
CITATION
--------
Please use the following citation when publishing results
obtained with NWChem:
Anchell, J.; Apra, E.; Bernholdt, D.; Borowski, P.; Bylaska, E.;
Clark, T.; Clerc, D.; Dachsel, H.; de Jong, W.A.; Deegan, M.;
Dupuis, M.; Dyall, K.; Elwood, D.; Fann, G.; Fruchtl, H.;
Glendenning, E.; Gutowski, M.; Harrison, R.; Hess, A.;
Jaffe, J.; Johnson, B.; Ju, J.; Kendall, R.; Kobayashi, R.;
Kutteh, R.; Lin, Z.; Littlefield, R.; Long, X.; Meng, B.;
Nichols, J.; Nieplocha, J.; Rendall, A.; Rosing, M.;Sandrone, G;
Stave, M.; Straatsma, T.;Taylor, H.; Thomas, G.; van Lenthe, J.;
Windus, T; Wolinski, K.; Wong, A.; Zhang, Z.; "NWChem, A
Computational Chemistry Package for Parallel Computers,
Version 3.3.1" (1999),
Pacific Northwest National Laboratory,
Richland, Washington 99352-0999, USA.
REFERENCES
----------
Where appropriate, please cite the following reference(s)
when publishing results obtained with NWChem:
1. D. E. Bernholdt, E. Apra, H. A. Fruchtl, M.F. Guest, R. J. Harrison,
R. A. Kendall, R. A. Kutteh, X. Long, J. B. Nicholas, J. A. Nichols,
H. L. Taylor, A. T. Wong, G. I. Fann, R. J. Littlefield and J. Nieplocha,
"Parallel Computational Chemistry Made Easier: The Development of NWChem,"
Int. J. Quantum Chem. Symposium 29, 475-483 (1995).
Total times cpu: 231.0s wall: 247.6s