&GLOBAL
  PROGRAM_NAME ATOM
  PROJECT Cu
&END GLOBAL

&ATOM
  ELECTRON_CONFIGURATION [Ar] 3d10 4s1
  ELEMENT Cu
  &METHOD
    METHOD_TYPE KOHN-SHAM
    RELATIVISTIC ZORA(MP)
    &XC
      &XC_FUNCTIONAL
        &PBE
        &END PBE
      &END XC_FUNCTIONAL
    &END XC
  &END METHOD
&END ATOM
