&GLOBAL
  PROJECT tio
  RUN_TYPE ENERGY_FORCE
&END GLOBAL

# MOPAC2007 REFERENCE:
#
#          FINAL HEAT OF FORMATION =        202.66349 KCAL =     847.94404 KJ
#
#
#          TOTAL ENERGY            =       -349.25172 EV
#          ELECTRONIC ENERGY       =       -539.07341 EV  POINT GROUP:     C*v
#          CORE-CORE REPULSION     =        189.82169 EV
#
&FORCE_EVAL
  METHOD Quickstep
  &DFT
    &PRINT
      &AO_MATRICES
        CORE_HAMILTONIAN
        DENSITY
        KOHN_SHAM_MATRIX
        OMIT_HEADERS
        OVERLAP
      &END AO_MATRICES
      &MO
        EIGENVALUES
        EIGENVECTORS
      &END MO
    &END PRINT
    &QS
      METHOD PM6
      &SE
        ANALYTICAL_GRADIENTS F
        STO_NG 6
      &END SE
    &END QS
    &SCF
      SCF_GUESS MOPAC
    &END SCF
  &END DFT
  &SUBSYS
    &CELL
      ABC 20.0 20.0 20.0
      PERIODIC NONE
    &END CELL
    &COORD
      Ti    .00000000   .00000000   .00000000
      O    .00000000   .80000000   .80000000
    &END COORD
    &PRINT
      &KINDS
        BASIS_SET
        SE_PARAMETERS
      &END KINDS
    &END PRINT
  &END SUBSYS
&END FORCE_EVAL
