&GLOBAL
  PROJECT Ca
  PROGRAM_NAME ATOM
&END GLOBAL
&ATOM
  ELEMENT Ca
  ELECTRON_CONFIGURATION CORE 3s2 3p6 4s2
  CORE [Ne]
  EXCHANGE_INTEGRALS ANALYTIC
  &METHOD
     METHOD_TYPE  KOHN-SHAM
     &XC
       &XC_FUNCTIONAL PBE0
       &END XC_FUNCTIONAL
     &END XC
  &END METHOD
  &POTENTIAL
    PSEUDO_TYPE GTH
    POTENTIAL_NAME GTH-PBE-q10
  &END POTENTIAL
  &PP_BASIS
     BASIS_TYPE CONTRACTED_GTO
     BASIS_SET DZVP-GTH-PBE
  &END PP_BASIS
&END ATOM
